Controllable Manipulation of Large-Volume Droplet on Non-Slippery Surfaces Based on Triboelectric Contactless Charge Injection.

Controllable droplet manipulation is crucial in diverse scientific and engineering fields. Traditional electric-based methods usually rely on commercial high-voltage (HV) power sources, which are typically bulky, expensive, and potentially hazardous. The triboelectric nanogenerator (TENG) is a highly studied device that can generate HV output with limited current, showing great potential in droplet manipulation applications. However, current TENG-based approaches usually utilize traditional free-standing TENGs that produce short-pulsed alternating-current signals. This limitation hinders continuous electrostatic forces necessary for precise droplet control, leading to complex circuitry and suboptimal droplet motion control in terms of volume, distance, direction, and momentum. Here, a triboelectric contactless charge injection (TCCI) method employing a novel dual-functional triboelectric nanogenerator (DF-TENG), is proposed. The DF-TENG can produce both high voltage and constant current during unidirectional motion, enabling continuous corona discharges for contactless charge injection into the droplets. Using this method, a large-volume droplet (3000 µL) can be controlled with momentum up to 115.2 g mm s-1 , quintupling the highest value recorded by the traditional methods. Moreover, the TCCI method is adaptable for a variety of non-slippery substrates and droplets of different compositions and viscosities, which makes it an ideal manipulation strategy for droplet transport, chemical reactions, and even driving solids.

A Bistable Triboelectric Nanogenerator for Low-Grade Thermal Energy Harvesting and Solar Thermal Energy Conversion.

Converting ubiquitous ambient low-grade thermal energy into electricity is of great significance for tackling the fossil energy shortage and environmental crisis but poses a considerable challenge. Here, a novel thermal-driven triboelectric nanogenerator (TD-TENG) is developed, which utilizes a bimetallic beam with a bi-stable dynamic feature to induce continuous mechanical oscillations, and the mechanical motion is then converted into electric power using a contact-separation TENG. The thermal process inside the device is systematically investigated and effective thermal management is conducted accordingly. After optimization, the TD-TENG can produce a power density of 323.9 mW m-2 at 59.5 °C, obtaining the highest record of TENG-based thermal energy harvesters. Besides, the first prototype of TENG-based solar thermal harvester is successfully demonstrated, with a power density of 364.4 mW m-2 . Moreover, the TD-TENG can harvest and dissipate the heat at the same time, exhibiting great potential in over-heated electronics protection as well as architectural energy conservation. Most importantly, the operation temperature range of the TD-TENG is tunable by adjusting the bimetal parameters, allowing the device a wide and flexible working thermal gradient. These unique properties validate the TD-TENG is a simple, feasible, cost-effective, and high-efficient low-grade thermal energy harvester.

A Dual-Functional Triboelectric Nanogenerator Based on the Comprehensive Integration and Synergetic Utilization of Triboelectrification, Electrostatic Induction, and Electrostatic Discharge to Achieve Alternating Current/Direct Current Convertible Outputs.

Traditional alternating current (AC) and direct current (DC) triboelectric nanogenerators (TENGs), which are implemented via the pairwise coupling of triboelectrification, electrostatic induction, and electrostatic discharge, have been widely explored in various fields. In this work, the comprehensive integration and synergetic utilization of triboelectrification, electrostatic induction, and electrostatic discharge in a single device for the first time is realized, achieving a dual-functional TENG (DF-TENG) to produce an AC/DC convertible output. Distinguishing from the conventional TENGs, the coupling of triboelectrification and electrostatic discharge enables charge circulation between the dielectric tribo-layers, while electrostatic induction realizes charge transfer in the external circuit. This novel energy conversion mechanism has been proven to be applicable to a variety of materials, including polymers, fabrics, and semiconductors. The output mode of the DF-TENG can be tuned by adjusting the slider motion state, and its constant output current and power density can reach 1.51 mA m-2 Hz-1 and 398 mW m-2 Hz-1 , respectively, which are the highest records reported for constant DC-TENGs to date. This work not only provides a paradigm shift to achieve AC/DC convertible output, but it also exhibits high potential for extending the TENG design philosophy.

A Mutual Boosting Self-Excitation Hybrid Cell for Harvesting High Entropy Energy at 32% Efficiency.

Triboelectric nanogenerators (TENGs) and dielectric elastomer generators (DEGs) are potentially promising energy conversion technologies, but they still have limitations due to their own intrinsic characteristics, including the low energy output of TENGs caused by the air breakdown effect, and external polarization voltage requirement for DEGs, which severely limit their practical applications. Herein, coupling TENG with DEG is proposed to build a mutual beneficial self-excitation hybrid generator (named TDHG) for harvesting distributed and low-quality mechanical energy (high entropy energy). Experimental results demonstrate that the output charges of this TDHG are enhanced by fivefold of that of the conventional charge-excitation TENG, and continuous operation of DEG is also realized by simple mechanical triggering. More importantly, owing to the high peak power contributed by TENG and the long output pulse duration guaranteed by DEG, the TDHG realizes a much higher energy conversion efficiency of 32% in comparison to either the TENG (3.6%) or DEG (13.2%). This work proposes a new design concept for hybridized energy harvester toward highly efficient mechanical energy harvesting.

Anti-Overturning Fully Symmetrical Triboelectric Nanogenerator Based on an Elliptic Cylindrical Structure for All-Weather Blue Energy Harvesting.

Triboelectric nanogenerators (TENGs) have shown promising potential for large-scale blue energy harvesting. However, the lack of reasonable designs has largely hindered TENG from harvesting energy from both rough and tranquil seas. Herein, a fully symmetrical triboelectric nanogenerator based on an elliptical cylindrical structure (EC-TENG) is proposed for all-weather blue energy harvesting. The novel elliptical cylindrical shell provides a unique self-stability, high sensitivity to wave triggering, and most importantly, an anti-overturning capability for the EC-TENG. Moreover, benefiting from its internal symmetrical design, the EC-TENG can produce energy normally, even if it was overturned under a rude oscillation in the rough seas, which distinguishes this work from previous reported TENGs. The working mechanism and output performance are systematically studied. The as-fabricated EC-TENG is capable of lighting 400 light-emitting diodes and driving small electronics. More than that, an automatic monitoring system powered by the EC-TENG can also monitor the water level in real-time and provide an alarm if necessary. This work presents an innovative and reliable approach toward all-weather wave energy harvesting in actual marine environments.

Magnetic Array Assisted Triboelectric Nanogenerator Sensor for Real-Time Gesture Interaction.

In human-machine interaction, robotic hands are useful in many scenarios. To operate robotic hands via gestures instead of handles will greatly improve the convenience and intuition of human-machine interaction. Here, we present a magnetic array assisted sliding triboelectric sensor for achieving a real-time gesture interaction between a human hand and robotic hand. With a finger's traction movement of flexion or extension, the sensor can induce positive/negative pulse signals. Through counting the pulses in unit time, the degree, speed, and direction of finger motion can be judged in real-time. The magnetic array plays an important role in generating the quantifiable pulses. The designed two parts of magnetic array can transform sliding motion into contact-separation and constrain the sliding pathway, respectively, thus improve the durability, low speed signal amplitude, and stability of the system. This direct quantization approach and optimization of wearable gesture sensor provide a new strategy for achieving a natural, intuitive, and real-time human-robotic interaction.

Switched-capacitor-convertors based on fractal design for output power management of triboelectric nanogenerator.

Owing to the advantages of integration and being magnet-free and light-weight, the switched-capacitor-convertor plays an increasing role compared to traditional transformer in some specific power supply systems. However, the high output impedance and switching loss largely reduces its power efficiency, due to imperfect topology and transistors. Herein, we propose a fractal-design based switched-capacitor-convertors with characteristics including high conversion efficiency, minimum output impedance, and electrostatic voltage applicability. As a double-function output power management system for triboelectric nanogenerators, it delivers over 67 times charge boosting and 954 W m-2 power density in pulse mode, and achieves over 94% total energy transfer efficiency in constant mode. The establishment of the fractal-design switched-capacitor-convertors provides significant guidance for the development of power management toward multi-functional output for numerous applications. The successful demonstration in triboelectric nanogenerators also declares its great potential in electric vehicles, DC micro-grids etc.

Polydirectional Microvibration Energy Collection for Self-Powered Multifunctional Systems Based on Hybridized Nanogenerators.

Vibrations in the environment are usually distributed over a wide frequency spectrum in multiple directions and a weaker amplitude, which makes most of the current vibrational energy collectors limited in practical environmental applications. Herein, a triboelectric-electromagnetic hybridized nanogenerator (TEHG) for low-frequency random microvibrational energy harvesting in all directions and a wide working bandwidth is fabricated. The output peak power of a triboelectric nanogenerator (TENG) up to 3.65 mW is realized (θ = 0.4 rad, f = 1 Hz). In addition, a real self-powered seawater splitting system and electrochemical cathodic protection system are fabricated, directly converting blue energy to hydrogen energy, and the ships can achieve self-protection against corrosion. Furthermore, relying on the linear relationship between the number of peaks and the amplitude of vibration, a highly sensitive self-powered vibration amplitude sensor system based on LabVIEW software is achieved, which can be used as an amplitude detection of bridges and earthquake monitoring, etc. This work is an important development for harvesting low-frequency random multiple direction microvibrational energy over a wide working bandwidth and the bright future of blue energy. In addition, it has been successfully applied to the power supply of portable electronic equipment, environmental monitors, and self-powered systems.

An Ultra-Durable Windmill-Like Hybrid Nanogenerator for Steady and Efficient Harvesting of Low-Speed Wind Energy.

Wind energy is one of the most promising and renewable energy sources; however, owing to the limitations of device structures, collecting low-speed wind energy by triboelectric nanogenerators (TENGs) is still a huge challenge. To solve this problem, an ultra-durable and highly efficient windmill-like hybrid nanogenerator (W-HNG) is developed. Herein, the W-HNG composes coupled TENG and electromagnetic generator (EMG) and adopts a rotational contact-separation mode. This unique design efficiently avoids the wear of friction materials and ensures a prolonged service life. Moreover, the generator group is separated from the wind-driven part, which successfully prevents rotation resistance induced by the friction between rotor and stator in the conventional structures, and realizes low-speed wind energy harvesting. Additionally, the output characteristics of TENG can be complementary to the different performance advantages of EMG to achieve a satisfactory power production. The device is successfully driven when the wind speed is 1.8 m s-1, and the output power of TENG and EMG can achieve 0.95 and 3.7 mW, respectively. After power management, the W-HNG has been successfully applied as a power source for electronic devices. This work provides a simple, reliable, and durable device for improved performance toward large-scale low-speed breeze energy harvesting.